The small tank will fill your central heating the big tank fills your cylinder. Assuming it’s piped correctly the only place these to waters come close is in the coil in the cylinder, central heating water inside, domestic hot water outside. There could be a small pinhole in your coil meaning that when it heats and expands water from the smaller tank is able to pass into the domestic hot water. This then effectively makes it all one circuit no longer separate so the two tanks in the loft will try and achieve the same water level. This will only be the case though if the water level in the smaller tank is higher than that in the larger tank otherwise the same would happen only in reverse