if you say that the boiler runs ok when pressurised but loses pressure overnight, probably what's happening is the expn vessel has failed and this means when the boiler runs, there's nowhere for the hw to expand and the prv operates until 3 bar is established, then everything is tickety until the heating goes off, water cools, pressure drops and next morning boiler wont work due to low system pressure. So ask engineer to check expn vessel first before looking at prv and other leak possibilities.
from memory doesn't gsr state you shouldn't work on a gas appliance without access to the mfis