Interesting... when I pulled the flexi off the condensate and piped it in to a bucket then fired up the system from cold, we got about 2 litres of water in an hour... this seems a hell of a lot. Other information, he has a 50 litre expansion vessel for 2 floors , 21 large radiators in total.
I have been today and stuck a pressure gauge on a towel rail, isolated the flow and return at the boiler, and left the loop heating the hot water cylinder ( the ch thermostat is set to 5, so it should not kick in at all )
I have set it at 2 bar because there are some old compression fittings in the system that I dont want to blow.
So the boiler is being tested at the same time as the ch loop being isolated. I will update on the results.
Thanks for all your help so far guys.