Towel on floor, close both valves, then remove air vent bleed screw. Open one valve at a time. On pressurised system, water will exit rad as a jet stream and can be caught in bucket.
This will confirm both valves function correctly. Will also clear air locks in system and stands good chance of forcing through any sludge causing reduced flow through valve.
If necessary top up pressure, because when pressure drops to zero a vacuum is created and water will stop flowing from rad. Opening, closing and reopening valve and gentle tapping is often sufficient to promote flow.