If all rads are producing their rated output then rad demand ~ 9.4kw.
UFH, 8LPM? at say a dT of 8C= 4.45kw. total, assuming no DHW = 13.85kw.
But, by calculation, boiler output at a flowrate of 1.42m3/hr @ dT of 12C, (70-58) is 19.82kw, 1.42x16.67x60x12/860, so again something not adding up, I suspect the pump is not now providing the correct data as one, its head at 3.7m can hardly even overcome the boiler Hx loss and two, by calc, the pump at those values is running at a efficiency of 54.85%, seems unlikely IMO, so again maybe reduce d.0 to a few kw below what your present calculated demand is, from pump flow&boiler dT and the flow temp should fall a bit below its SP, this will show up something.