Hi Mike,
Just gone back to the wiring having left it for a while. I have sort of solved the riddle of the overrun. From what you have said about taking the brown from the pump and connecting it to the live pump on the boiler I need to find which one of the 3 grey cables has the pump live in it. From working out which is which, one brown is to the timer,one brown goes to the boiler live and one brown to the pump live. At the wiring terminal I can find the timer live by just taking one of the browns from the grey cables out to see when the timer has no power. So the other 2 browns will be the pump live and boiler live,will it be ok to remove each in turn and connect it to the live on the pump in a spare terminal on the block to see which is which without blowing anything up? If I connect it to the boiler live then the pump will just run all the time and I know it will be the wrong one. I know I am crazy but sometimes it is more rewarding if you solve these things yourself (with help from clever people).
Many thanks for your help.