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reducing

A reducing agent (also called a reductant, reducer, or electron donor) is an element or compound that loses or "donates" an electron to an electron recipient (called the oxidizing agent, oxidant, or oxidizer) in a redox chemical reaction. The oxidation state, which describes the degree of loss of electrons, of the reducer increases while that of the oxidizer decreases; this is expressed by saying that reducers "undergo oxidation" and "are oxidized" while oxidizers "undergo reduction" and "are reduced". Thus, reducing agents "reduce" oxidizers by reducing (decreasing) their oxidation state while oxidizing agents "oxidize" reducers by increasing their oxidation state.
To clarify, in a redox reaction, the agent whose oxidation state increases, that "loses/donates electrons", that "is oxidized", and that "reduces" is called the reducer or reducing agent, while the agent whose oxidation state decreases, that "gains/receives electrons", that "is reduced", and that "oxidizes" is called the oxidizer or oxidizing agent.
A reducing agent is thus oxidized by an oxidizer when it loses electrons that are gained by this oxidizing agent, which itself is simultaneously reduced by the reducer.
In their pre-reaction states, reducers have extra electrons (that is, they are by themselves reduced) and oxidizers lack electrons (that is, they are by themselves oxidized). A reducing agent typically is in one of its lower possible oxidation states and is known as the electron donor. Examples of reducing agents include the earth metals, formic acid, oxalic acid, and sulfite compounds.
For example, consider the overall reaction for aerobic cellular respiration:

C6H12O6(s) + 6O2(g) → 6CO2(g) + 6H2O(l)The oxygen (O2) is being reduced, so it is the oxidizing agent. The glucose (C6H12O6) is being oxidized, so it is the reducing agent.
In organic chemistry, reduction usually refers to the addition of hydrogen to a molecule, though the aforementioned definition still applies. For example, the oxidizing agent benzene is reduced to cyclohexane in the presence of a platinum catalyst:

C6H6 + 3 H2 → C6H12Historically, reduction referred to the removal of oxygen from a compound, hence the name 'reduction'. An important example of this phenomenon occurred during the Great Oxidation Event, in which biologically−produced molecular oxygen (dioxygen (O2), an oxidizer and electron recipient) was added to the early Earth's atmosphere, which was originally a weakly reducing atmosphere containing reducing gases like methane (CH4) and carbon monoxide (CO) (along with other electron donors) and practically no oxygen because any that was produced would react with these or other reducers (particularly with iron dissolved in sea water), resulting in their removal.
By using water as a reducing agent, aquatic photosynthesizing cyanobacteria produced this molecular oxygen as a waste product.
This O2 initially oxidized the ocean's dissolved ferrous iron (Fe(II) − meaning iron in its +2 oxidation state) to form insoluble ferric iron oxides such as Iron(III) oxide − (Fe(II) lost an electron to the oxidizer and became Fe(III), meaning iron in its +3 oxidation state) that precipitated down to the ocean floor to form banded iron formations, thereby removing the oxygen (and the iron).
The rate of production of oxygen eventually exceeded the availability of reducing materials that removed oxygen, which ultimately led Earth to gain a strongly oxidizing atmosphere containing abundant oxygen (like the modern atmosphere). The modern sense of donating electrons is a generalization of this idea, acknowledging that other components can play a similar chemical role to oxygen.

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  1. S

    Noisy megaflo pressure reducing valve

    hello there, I have a megaflo unvented system everything works fine apart from the prv valve shown on the pic. Every time a tap opens or toilet flashed this prv makes noise. Spoke to guy who fitted the system and he said dont have much to say other than replacing with e new one. Just...
  2. D

    Pressure reducing valve

    Hi all, My pressure reducing value has failed on my unvented cylinder, my plumber has already changed the potable expansion vessel and prv and cold water is still running through the tundish. I hate being the annoying Googling customer, but I've found a Honeywell pressure reducing value on...
  3. A

    Megaflo pressure reducing valve

    Hi everyone, Was called to a megaflo last night, no water coming from any taps. Followed the recharge instructions but made no difference. I heard gurgling but no discharge appeared and the gurgling stopped after approx 3 minutes. I spoke to heatrae sadia who recommended new pressure...
  4. K

    Choice of Pressure reducing valve

    Renovating bathroom just now and the wife wants mixer taps throughout. Normal single handle hobbj on the sink and a fancy traditional style beast on the bath. Hot water is supplied from unvented cylinder at 2 bar closed pressure, 1.5 bar ish when flowing full tilt. Cold is supplied from mains...
  5. Inverness

    Oil pressure reducing valve

    hi guys, I'm planning to locate a new oil tank but the problem is the height will most likely to be greater than 4 meters from oil pump. I know you can use a oil pressure reducing valve have anyone used this before?.
  6. R

    zip pressure reducing valve operation

    Thought I had a problem with an Ariston 30L water heater in a village hall whereby the hot water flow has steadily reduced to almost nothing over a period of a year. When you open the hot water tap you get a burst of water then it slows and stops after only a small amount has come out...
  7. M

    Microbore advice - please! - New run pipe size before reducing to microbore

    Hi All I want to add a radiator to a microbore system; the supply and return pipes are all 22 mm feeding a mixture of 10 mm or 8 mm microbore which are taken directly from the ends of the 22 mm pipes. I plan to "T" into the 22 mm supply and return pipes with a run of "large bore" pipe before...
  8. A

    Flamco pressure reducing valve

    This is a pressure reducing valve correct?
  9. S

    Megaflow 3 bar pressure reducing valve placement

    Hi, Have lived in our house for around 10 years and always had bad pressure if more than one tap is running, toilet is flushed etc(hot and cold). We have (what I believe to be) a mains pressure system with a non vented Megaflow cylinder. We are about to install a new thermostatic shower and...
  10. P

    Fog Horn noise when using Hot Water - Pressure Reducing Valve recently replaced

    A few months back the expansion vessel from the mains water supply failed and I had the vessel and the pressure reducing valve replaced. As part of the replacement the expansion vessel was fitted with a copper tube instead of the flexible hose that was originally used. Since the work was done...
  11. D

    Brass fitting, help needed to identifi the thread type

    hello everyone, i hope someone can help me out. i,m trying to reuse an old wrap around boiler and i have run into a snag. to cut a long story short, there is 4 X 22mm brass fittings on the boiler so i bought a 22mm straight brass coupling to test. fits as it should on one fitting on the boiler...
  12. P

    flamco pressure reducing valve?

    Hi chaps and chapesses I have a customer with a leaking Flamco pressure reducing valve see pics it seems to be leaking from the gauge which is full of water. looks like it was fitted as an afterthought the way the pipework runs. customer now has a combi in so probably has a new prv fitted...
  13. I

    Cold mains water hammer when taps are turn ON?

    The cold mains is in 22mm copper on a pipe run to to a bath and basin taps next to each other. The mains water is 4 bar static, no PRV or check valves. The bang happens seconds after the cold tap is turned on at either the cold bath or basin tap. There is a 0.5 litre potable water expansion...
  14. S

    pressure reducing valve cartridge leaking

    Hi all, I think the pressure reducing valve cartridge on my pressure reducing valve is leaking. The pipe size is 22mm. Where can I find a replacement for it? I am clue less about what pressure and type it is. here is a picture https://goo.gl/photos/3UeYrT7gdt3rmhgcA Thanks Seb
  15. JCplumb

    Basin mixer, high cold pressure, 0.5 bar hot (gravity HWS)

    Got a customer who has called me in after an absolute nightmare with a cowboy builder and an ex-friend project managing her renovation. I feel really sorry for her, she was actually crying when explaining what had gone on when I first went round. Anyway, she has a basin mixer that she really...
  16. D

    offset reducing nipple

    Hello everyone, I am struggling to find a 1/2" to 3/4" offset reducing nipple. It is male to male. Attached a photo. Would someone be able to message me where I can buy this item? Many thanks, david
  17. G

    Continuing pressure reducing debate.

    Shaun kindly recommended: "Altecnic - 3/4" MBSP x 3/4" MBSP - Prescal Series 535 Dial Up Pressure Reducing Valve With Presure Gauge - 535051 Altecnic - 3/4" FBSP x 3/4" FBSP - Y Pattern Strainer - AI-500022 and a good pressure reducing valve shouldn't change/lower the flow" And it looks a...
  18. G

    Pressure reducing valve - problem with

    Hi, I have so far fitted 2 pressure reducing valves on our mains input water supply (6bar) to reduce it to 3-4 bar. Both have failed, the pressure creeping up slowly to 6bar after a few weeks of use. I am assuming it is could be grit coming in from the main and lodging between the poppet...
  19. C

    caleffi pressure reducing valve/inlet group

    Does any one no if you can adjust the pressure reducing valve on these and if so how? thanks :)
  20. S

    3 Bar Pressure Reducing Valve - Knocking

    Hello - first up I am not a plumber, so am hoping that my problem is one of those really easy things to sort out if I was! The 3 bar pressure reducing valve fitted to the cold water inlet pipe to my Heatrae Sandia Megaflow in the airring cupboard has just started to make a thumping or...
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