Yipppppeeeeeee, I may of gave a little bit of advice, instead of asking for it.:tounge_smile:
Ok not sure why you have two greys, at the join, unless you have a new coloured coded cable, from the clock to the join.
(new colours, brown/black/grey).
But if you identify, the grey of the valve, and this has 230volts on it, and at the same time, the white of the valve, has 230volts on it, then you should have 230volts, on the orange of the valve.
The valve uses the grey to signal to the orange, to fire the boiler up.
Power on the white only, holds it in mid-position.
So central heating and hot water in that position.
By gettin 230v on white, you have proved the clock and stat are ok.:tounge_smile: