The vent pipe is/should be 22mm and the cold feed is 15mm, are you sure its not the cold feed you are looking at.Hi apologies
The expansion copper pipe is 15mm not 25mm...finger trouble
Is the pump located upstairs in the hot press and the boiler downstairs, if so, and if you have zoned CH and HW then you will have at least two motorized valves fairly close to the pump, they may be located above the pump or below it, between the pump and these you might see something like the above arrangement (without the air jec).
Also go to the attic and have a look at your small cistern (Feed & expansion or F&E cistern for short) and see where the vent goes up and over it and also the cold feed which will come from the side or end of this cistern, you can then follow it and see where it is teed into the system.
Might look something like this: (This pump is pumping downwards)
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