Hmm I can't really think of anything else to suggest. Seems like you'd already covered all the things I know.
Is yours a systerm or combi?
I don't think d.5 is an adjustable setting. I think it's a read out of the flow temp the boiler is trying to achieve: if you have a smart contoller the...
From my (limited) understanding, your old thermostat would simply have worked as an on/off switch. I believe the Nest operates in the same way (i.e. on/off).
The OP had a Vaillant weather compensation device fitted initially and forgot to remove the old receiver so boiler flow temp was still...
Yes this is my understanding of the Nest system hence why I wondered why the OP removed a modulating system and replaced it with an on/off setup as offered by Nest.
Was it to have remote access via smartphone?
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